Yes, chest exercises can build up the muscle under the breasts and give the upper chest a more filled-out look, and sometimes even give a little lift. But, remember you can't change the breast itself with exercise, just the muscles underneath.
Everyone should be doing weight training for all major muscle groups -- don't work just one body part. Kathy Smith's Lift Weight to Lose Weight is a GREAT way to start, and has lots of good chest exercises.
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